(PDF) Potassium Iodide-Modified Lead-Free Cs3Bi2I9 …

Lead-free, bismuth-based perovskite solar cells (PSCs) are promising, non-toxic, and stable alternatives to lead-based PSCs, which are environmentally harmful and highly unstable under deprived ...

Hysteresis-free perovskite solar cells made of potassium-doped …

Potassium-doped organometal halide perovskite solar cells (PSCs) of more than 20% power conversion efficiency (PCE) without I-V hysteresis were constructed.

Ethylammonium Bromide

Keywords: perovskite; solar cells; ethylammonium; potassium 1. Introduction Although silicon solar cells are widely used in the world, greater cost reduction and development of usability are needed for future solar cell devices. Perovskite solar cells are one of the alternate candidates for future photovoltaic devices [1–4], and the progress is

Vacancy healing for stable perovskite solar cells via bifunctional ...

Jiang et al. treated the formamidine and methylamine hybrid perovskite layer with phenethylammonium iodide (PEAI) to passivate the grain boundary defects and to fill the …

Potassium thiocyanate additive for PEDOT:PSS layer to fabricate ...

The commercialized poly(3,4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT:PSS) is usually used as hole transport layers (HTLs) in tin-based perovskite solar cells (TPSCs). However, the further development has been restricted due to the acidity that could damage the stability of TPSCs. Although the PEDOT:PSS solution can be diluted by water to …

Effects of potassium treatment on SnO2 electron transport layers …

SnO 2 has been studied intensively as an electron transport layer (ETL) for highly efficient metal halide perovskite solar cells. However, SnO 2 ETL frequently exhibits defect-related issues associated with the bulk SnO 2 and the perovskite/SnO 2 interface, and to passivate the defect states potassium ion has been used. In order to investigate the …

Stable high conversion efficiency of Quasi-2D perovskite solar cells ...

In this article, we introduce a simple and effective method to modify the quasi-2D (BA) 2 (MA) 3 Pb 4 I 13 perovskite solar cells by introducing potassium iodide as an additive. We found that the introducing K ion made perovskite film more compact, reduced the number of grain boundaries and regulated the band alignment.

Potassium iodide reduces the stability of triple-cation perovskite ...

We have systematically explored the effect of adding potassium iodide KI (0–20%) into a triple-cation (TC) perovskite precursor solution to determine whether it can be …

Potassium iodide reduces the stability of triple-cation perovskite ...

The addition of alkali metal halides to hybrid perovskite materials can significantly impact their crystallisation and hence their performance when used in solar cell devices. Previous work on the use of potassium iodide (KI) in active layers to passivate defects in triple-cation mixed-halide perovs …

Antimony Potassium Tartrate Stabilizes Wide-Bandgap …

Wide-bandgap (WBG) perovskites have been attracting much attention because of their immense potential as a front light-absorber for tandem solar cells. However, WBG perovskite solar cells (PSCs) generally exhibit undesired large open-circuit voltage (VOC) loss due to light-induced phase segregation and severe non-radiative recombination loss. Herein, …

Potassium iodide reduces the stability of triple-cation …

Potassium iodide reduces the stability of triple-cation perovskite solar cells† Tarek I. Alanazi, ab Onkar S. Game, a Joel A. Smith, a Rachel C. Kilbride, a Claire Greenland,a Rahul Jayaprakash ...

Facile eco-friendly process for upcycled sustainable perovskite solar cells

1. Introduction. Perovskite solar cells (PSCs) containing organic–inorganic lead halide perovskites as light harvests have developed into a critical photovoltaic (PV) technology due to their high certified power conversion efficiency (PCE) of ∼ 26.1 % and excellent operational stability over 9000 h under international electrotechnical commission standards [1], [2], [3], [4].

Potassium Incorporation for Enhanced Performance and Stability …

Here, cesium lead halide perovskite solar cells with enhanced performance and stability are demonstrated via incorporating potassium cations. Based on Cs 0.925 K 0.075 PbI 2 Br, the planar-architecture device achieves a power conversion efficiency of 10.0%, which is a remarkable record in the field of inorganic perovskite solar cells. In ...

Synergistic effect of potassium and iodine from potassium …

In this work, we employ potassium triiodide complex (KI 3) as an additive to optimize one-step gas-quenching process for high efficiency perovskite solar devices.The aim is to combine the benefits brought about by excess I 2 [14] (using KI 3 complex as the source) and the benefits brought about by potassium salt [22, 24, 25] (also using KI 3 complex as the …

Potassium Iodide-Modified Lead-Free Cs3Bi2I9 Perovskites for

Lead-free, bismuth-based perovskite solar cells (PSCs) are promising, non-toxic, and stable alternatives to lead-based PSCs, which are environmentally harmful and highly unstable under deprived air conditions. ... and highly improved photovoltaic performance by integrating different amounts of potassium iodide (KI) into a perovskite precursor ...

Iodide Management and Oriented Crystallization Modulation for …

Halide-related defects at the buried interface not only cause nonradiative recombination, but also seriously impair the long-term stability of perovskite solar cells …

Polysilane-Inserted Methylammonium Lead Iodide Perovskite Solar Cells ...

Polysilane-inserted CH3NH3PbI3 perovskite photovoltaic devices combined with potassium and formamidinium iodides were fabricated and characterized. Decaphenylcyclopentasilane layers were inserted at the perovskite/hole transport interface and annealed across a temperature range of 180–220 °C. These polysilane-coated cells prevented …

Potassium gives perovskite-based solar cells an …

"This would enable perovskites to be used as versatile solar cells or as coloured LEDs, which are essentially solar cells run in reverse." In the study, the researchers altered the chemical composition of the perovskite …

Suppressing Residual Lead Iodide and Defects in ...

Added to this potassium ions can increase grain sizing and curtail ion movement at the grain borders. The combined effect is that a sequential-deposited polycrystalline perovskite solar cell with ...

Potassium Iodide Doping Strategy for High-Efficiency Perovskite Solar ...

Request PDF | On Jan 13, 2022, Lei Gao and others published Potassium Iodide Doping Strategy for High-Efficiency Perovskite Solar Cells Revealed by Ultrafast Spectroscopy | Find, read and cite all ...

Potassium Iodide-Modified Lead-Free Cs3Bi2I9 Perovskites …

PSCs, were rehabilitated by adding potassium iodide. These next-generation solar cells may be created as independent photovoltaic devices or colored LEDs, or they may be used to increase the efficiency of existing silicon-based solar cells. Perovskite solar cell (PSC) luminescence efficiencies are still significantly less than 100%,

Defects engineering for high-performance perovskite …

The solar to electrical power conversion efficiency (PCE) of perovskite solar cells has been rapidly improved from 3.9% to certified 22.7% due to the extensive efforts on film deposition methods ...

Universal Approach toward Hysteresis-Free Perovskite Solar Cell …

Organic–inorganic halide perovskite is believed to be a potential candidate for high efficiency solar cells because power conversion efficiency (PCE) was certified to be more than 22%. Nevertheless, mismatch of PCE due to current density (J)–voltage (V) hysteresis in perovskite solar cells is an obstacle to overcome. There has been much lively debate on the …

Vacancy healing for stable perovskite solar cells via bifunctional ...

Vacancy healing for stable perovskite solar cells via bifunctional potassium tartrate. Author links open overlay panel Jing Dou a, Yue Ma b, ... Jiang et al. treated the formamidine and methylamine hybrid perovskite layer with phenethylammonium iodide (PEAI) to passivate the grain boundary defects and to fill the surface iodine vacancies ...

Stable high conversion efficiency of Quasi-2D perovskite solar …

In this article, we introduce a simple and effective method to modify the quasi-2D (BA)2(MA)3Pb4I13 perovskite solar cells by introducing potassium iodide as an additive.

Potassium gives perovskite-based solar cells an efficiency boost

"This would enable perovskites to be used as versatile solar cells or as coloured LEDs, which are essentially solar cells run in reverse." In the study, the researchers altered the chemical composition of the perovskite layers by adding potassium iodide to perovskite inks, which then self-assemble into thin films.

Potassium Iodide Doping Strategy for High-Efficiency Perovskite Solar ...

The doping strategy is considered to be an effective method for regulating the performance of perovskite solar cells, yet its efficiency is still far below what has been anticipated. Here, we systematically investigate the regulatory mechanisms of the performance of perovskites by exploiting potassium iodide (KI) doping.

Incorporating Potassium Citrate to Improve the Performance of …

[1-6] PSCs that include an alloy of perovskites based on tin and lead divalent metal cations have been identified as a promising avenue for achieving theoretical power conversion efficiencies higher than 30% in single junction solar cells and a critical component for realizing ultra-high efficiencies of up to 41% in all-perovskite tandem solar ...

Effects of the Addition of Copper Chloride and …

The perovskite solar cells have a photovoltaic performance with reduced durability due to the volatility of organic cations and toxic lead in the perovskite crystal as an active layer. The purpose of this research is to …

Ethylammonium Bromide

Perovskite solutions with added potassium iodide (KI) and ethylammonium bromide (EABr) were used to fabricate perovskite solar cells in ordinary air at 190 °C. The addition of EABr and KI induced (100)-oriented perovskite crystals, which resulted in the improvement in short-circuit current densities and conversion efficiencies. The short-circuit …

Potassium Iodide-Modified Lead-Free Cs3Bi2I9 Perovskites for …

These next-generation solar cells may be created as independent photovoltaic devices or colored LEDs, or they may be used to increase the efficiency of existing silicon-based solar cells. Perovskite solar cell (PSC) luminescence efficiencies are still significantly less than 100%, so there is an opportunity for development.

Potassium iodide reduces the stability of triple-cation perovskite ...

The addition of alkali metal halides to hybrid perovskite materials can significantly impact their crystallisation and hence their performance when used in solar cell devices. Previous work on …

Defects engineering for high-performance perovskite solar cells

The solar to electrical power conversion efficiency (PCE) of perovskite solar cells has been rapidly improved from 3.9% to certified 22.7% due to the extensive efforts on film deposition methods ...

Potassium iodide reduces the stability of triple-cation perovskite ...

By investigating perovskite solar cell performance with SnO2 or TiO2 electron transport layers (ETL), we propose that defect passivation using KI is highly sensitive to the composition of the ...

(PDF) Potassium Iodide-Modified Lead-Free Cs3Bi2I9

Lead-free, bismuth-based perovskite solar cells (PSCs) are promising, non-toxic, and stable alternatives to lead-based PSCs, which are environmentally harmful and highly unstable under deprived ...

Potassium gives perovskite-based solar cells an efficiency boost

The perovskite and potassium devices showed good stability in tests, and were 21.5% efficient at converting light into electricity, which is similar to the best perovskite-based solar cells and ...

Potassium iodide reduces the stability of triple-cation perovskite ...

We have systematically explored the effect of adding potassium iodide KI (0–20%) into a triple-cation (TC) perovskite precursor solution to determine whether it can be used to improve the efficiency of solar cell devices by passivating defect states in the perovskite and at the perovskite electron transport layer (ETL) interface.

Hysteresis-free perovskite solar cells made of potassium-doped ...

It is concluded that stagnation-less carrier transportation could minimise the I-V hysteresis of PSCs. Potassium-doped organometal halide perovskite solar cells (PSCs) of more than 20% power conversion efficiency (PCE) without I-V hysteresis were constructed. The crystal lattice of the organometal halide perovskite was expanded with increasing of the …

Stable high conversion efficiency of Quasi-2D perovskite solar …

In this article, we introduce a simple and effective method to modify the quasi-2D (BA) 2 (MA) 3 Pb 4 I 13 perovskite solar cells by introducing potassium iodide as an additive. …

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